Bis(pentafluorophenyl)boron azide:: synthesis and structural characterization of the first dimeric boron azide

被引：34

作者：

Fraenk, W ^{[1
]}

Klapötke, TM ^{[1
]}

Krumm, B ^{[1
]}

Mayer, P ^{[1
]}

机构：

[1] Univ Munich, Dept Chem, D-81377 Munich, Germany

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 08期

关键词：

D O I：

10.1039/b001103g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of (C6F5)(2)BCl with trimethylsilyl azide results in the formation of (C6F5)(2)BN3 1; evaporation of the stabilizing solvent results in irreversible dimerization yielding [(C6F5)(2)BN3](2) 1a as the first example of a dimeric boron azide; in the presence of pyridine a stable adduct (C6F5)(2)BN3. py 2 is isolated.

引用

收藏

页码：667 / 668

页数：2

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