The self-assembly between C2-symmetric (methanol)6 or S6-symmetric (ethanol)6 cyclohexamers and paddle-wheel dinuclear copper units leads to unique 1D polymer chains

被引：13

作者：

Benisvy, Laurent

Mutikainen, Ilpo

Quesada, Manuel

Turpeinen, Urho

Gamez, Patrick

Reedijk, Jan

机构：

[1] Leiden Univ, Leiden Inst Chem, Gorlaeus Labs, NL-2300 RA Leiden, Netherlands

[2] Univ Helsinki, Dept Chem, Inorgan Chem Lab, Helsinki 00014, Finland

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 35期

关键词：

D O I：

10.1039/b608220c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first crystallographic evidences of the theoretically suggested C-2-symmetric cyclohexameric form of liquid methanol and the S-6-symmetric cyclohexameric form of liquid ethanol are reported, trapped inside a hydrophilic pocket shielded by tert-butyl groups.

引用

页码：3723 / 3725

页数：3

共 18 条

[1]

BENEDEK G, 1988, ELEMENTAL MOL CLUSTE

[2] The structure of liquid ethanol: A neutron diffraction and molecular dynamics study [J].