Observation of the ''isomerization states'' of HCP by stimulated emission pumping spectroscopy: Comparison between theory and experiment

被引：31

作者：

Ishikawa, H ^{[1
]}

Nagao, C ^{[1
]}

Mikami, N ^{[1
]}

Field, RW ^{[1
]}

机构：

[1] MIT,DEPT CHEM,CAMBRIDGE,MA 02139

来源：

JOURNAL OF CHEMICAL PHYSICS | 1997年 / 106卷 / 07期

关键词：

D O I：

10.1063/1.473417

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Highly excited vibrational states of HCP (X) over tilde (1) Sigma(+) were investigated by stimulated emission pumping spectroscopy. Two distinct families of vibrational states were observed in the 13400-17500 cm(-1) energy region. One of them is ''normal-mode-type'' states, well characterized by polyads involving the bending (omega(2)) and CP stretching (omega(3)) vibrations. The other is delocalized ''isomerization states'' whose existence has been predicted by a recent theoretical study [J. Chem. Phys. 104, 10055 (1996)]. The present spectroscopic observations agree well with the theoretical predictions. (C) 1997 American Institute of Physics.

引用

页码：2980 / 2983

页数：4

共 10 条

[1] THE VIBRATION-ROTATION SPECTRUM OF METHINOPHOSPHIDE - THE OVERTONE BANDS 2-NU-1 AND 2-NU-3, THE SUMMATION BANDS NU-1+NU-2 AND NU-2+NU-3, AND THE DIFFERENCE BAND NU-1-NU-2 [J].