Fluorene-Based Materials and Their Supramolecular Properties

被引:132
作者
Abbel, Robert [1 ]
Schenning, Albertus P. H. J. [1 ]
Meijer, E. W. [1 ]
机构
[1] Eindhoven Univ Technol, Lab Macromol & Organ Chem, NL-5612 AZ Eindhoven, Netherlands
关键词
pi-conjugated oligomers; pi-conjugated polymers; fluorene copolymers; morphology; oligofluorenes; phase behavior; polyaromatics; polyfluorenes; self-assembly; self-organization; supramolecular structures; thin films; LIGHT-EMITTING-DIODES; SOLUBLE CONJUGATED POLYMERS; CIRCULARLY-POLARIZED ELECTROLUMINESCENCE; ALTERNATING POLYFLUORENE COPOLYMERS; ENERGY-TRANSFER PROPERTIES; CROSS-COUPLING REACTIONS; ORGANIC SOLAR-CELLS; SIDE-CHAIN LENGTH; BLOCK-COPOLYMERS; CHIROPTICAL PROPERTIES;
D O I
10.1002/pola.23499
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Fluorene-based pi-conjugated polymers and oligomers combine several advantageous properties that make them well-suited candidates for applications in organic optoelectronic devices and chemical sensors. This review highlights strategies to synthesize these materials and to tune their absorption and emission colors. Furthermore, methods to control their supra-molecular organization will be discussed. In many cases, a delicate interplay between the chemical structure and the processing conditions are found, resulting in a high sensitivity of both structural features and optical properties. (C) 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 4215-4233, 2009
引用
收藏
页码:4215 / 4233
页数:19
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