The first general method for the synthesis of transition-metal π complexes of an electronically diverse family of 1,2-azaborolyls

被引：36

作者：

Liu, SY ^{[1
]}

Hills, ID ^{[1
]}

Fu, GC ^{[1
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

ORGANOMETALLICS | 2002年 / 21卷 / 21期

关键词：

D O I：

10.1021/om020533b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A general method for the synthesis of new families of transition-metal-free 1,2-azaborolides'(3) has been developed, based on a readily available precursor (1). These azaborolides react with a variety of transition-metal electrophiles to produce an unprecedented array of eta(5)-azaborolyl adducts (4) (substituents bound to boron: nitrogen, oxygen, hydrogen, carbon, and phosphorus).

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页码：4323 / 4325

页数：3

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