Room-temperature solubility behavior of barium titanate in aqueous media

被引:68
作者
Neubrand, A [1 ]
Lindner, R [1 ]
Hoffmann, P [1 ]
机构
[1] Darmstadt Univ Technol, Dept Mat Sci, D-64287 Darmstadt, Germany
关键词
Incongruent dissolution;
D O I
10.1111/j.1151-2916.2000.tb01286.x
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In the present study, the incongruent dissolution of barium from barium titanate (BaTiO3) has been studied as a function of dispersion pH and powder volume fraction for two different BaTiO3 powders. In alkaline dispersions, the barium solubility strongly increases as the pH increases, as suggested by thermodynamic considerations. At pH <7, the barium solubility reaches a plateau, the height of which is dependent on the surface area of the powder and the solids loading of the slip. The BaTiO3 surface is completely depleted of barium in this region.
引用
收藏
页码:860 / 864
页数:5
相关论文
共 9 条
[1]  
ANDERSON DA, 1988, CERAMIC T, V1, P485
[2]  
BARRINGER EA, 1984, THESIS MIT CAMBRIDGE
[3]   The properties of aqueous phase suspensions of barium titanate [J].
BlancoLopez, MC ;
Rand, B ;
Riley, FL .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 1997, 17 (2-3) :281-287
[4]   SURFACE DECONTAMINATION TREATMENTS OF UNDOPED BATIO3 .1. POWDER AND GREEN BODY PROPERTIES [J].
HERARD, C ;
FAIVRE, A ;
LEMAITRE, J .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 1995, 15 (02) :135-143
[5]   LOW-TEMPERATURE AQUEOUS PREPARATION OF BARIUM METATITANATE POWDERS [J].
NANNI, P ;
LEONI, M ;
BUSCAGLIA, V ;
ALIPRANDI, G .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 1994, 14 (01) :85-90
[6]   THERMODYNAMIC STABILITY AND KINETICS OF PEROVSKITE DISSOLUTION [J].
NESBITT, HW ;
BANCROFT, GM ;
FYFE, WS ;
KARKHANIS, SN ;
NISHIJIMA, A .
NATURE, 1981, 289 (5796) :358-362
[7]  
Osseo-Asare K., 1988, Ceramic Transactions, Ceramic Powder Science, VVol. 1, pp. 47
[8]  
RING TA, 1996, FUNDAMENTALS CERAMIC, P474
[9]  
UTECH B, 1990, THESIS PENNSYLVANIA