The crystal and molecular structure of one of the possible conformers of "the smallest piece of ice" - A solid-state isolation of a hydrogen bonded water hexamer trapped within channels of a crystal of a dirhodium molecule

被引：11

作者：

Bernal, I ^{[1
]}

Bear, JL ^{[1
]}

机构：

[1] Univ Houston, Dept Chem, Houston, TX 77204 USA

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2002年 / 32卷 / 11期

关键词：

dirhodium molecule; antineoplastic; hexameric cluster;

D O I：

10.1023/A:1021148910894

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Reexamination of our study of [Rh-2(HNOCCH3)(4)(2H2O)] . 3H(2)O (Ahsan, M. Q.; Bernal, I.; Bear, J. L. Inorg. Chem. 1986, 26, 260) showed it to be interesting not just because the dirhodium molecule is an antineoplastic but because it contains a hexameric cluster of waters trapped in Rh-Rh lattice cavities. It may well provide an interesting model for the "smallest piece of ice".

引用

页码：485 / 488

页数：4

共 15 条

[1] REACTION OF RH2(OOCCH3)4 WITH ACETAMIDE - CRYSTAL AND MOLECULAR-STRUCTURE OF [RH2(HNOCCH3)4.2H2O].3H2O [J].