Unexpected conversion of vinyl sulfoxides into carbonyl compounds by means of iodotrimethylsilane

被引：7

作者：

Aversa, MC

Barattucci, A

Bonaccorsi, P

Bruno, G

Giannetto, P

Policicchio, M

机构：

[1] Univ Messina, Dipartimento Chim Organ & Biol, I-98166 Messina, Italy

[2] Univ Messina, Dipartimento Chim Inorgan, I-98166 Messina, Italy

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 22期

关键词：

carbonyl compounds; desulfurization; iodotrimethylsilane; sulfoxides;

D O I：

10.1016/S0040-4039(00)00612-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The unexpected and previously unknown TMSI-promoted conversion of cl,P-unsaturated sulfoxides into carbonyl compounds and disulfides is described. It occurs in good yields under mild conditions. The examples provided support the generality and efficiency of this procedure which acts as a good method for removing the sulfinyl group with the advantage of transforming-the vinyl sulfoxides into carbonyl compounds. (C) 2000 Elsevier Science Ltd. All rights reserved.

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收藏

页码：4441 / 4445

页数：5

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