Synthesis and catalytic activity of DAB-dendrimer encapsulated Pd nanoparticles for the Suzuki coupling reaction

被引：45

作者：

Lemo, Julietta ^{[1
]}

Heuze, Karine ^{[1
]}

Astruc, Didier ^{[1
]}

机构：

[1] Univ Bordeaux 1, Grp Nanosci Mol & Catalyse, LCOO, UMR 5802, F-33405 Talence, France

来源：

INORGANICA CHIMICA ACTA | 2006年 / 359卷 / 15期

关键词：

dendrimers; nanoparticles; palladium; catalysis; METAL NANOPARTICLES; HYDROGENATION; NANOCLUSTERS; COMPLEXES; GOLD;

D O I：

10.1016/j.ica.2005.12.070

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Palladium based dendrimer-encapsulated metal nanoparticles (DEMNs) are prepared by reduction of an aqueous solution of palladium (II) and five generations of amino terminated dendrimers (DAB (diammobutane) dendrimers). The average size of the palladium nanoparticles formed is 1.7-2.8 nm. Catalytic performances of these DEMNs have been studied in the Suzuki cross-coupling reaction. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：4909 / 4911

页数：3

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