Porosity control of porous silicon carbide ceramics

被引:105
作者
Chae, Su-Ho [1 ]
Kim, Young-Wook [1 ]
Song, In-Hyuck [2 ]
Kim, Hai-Doo [2 ]
Narisawa, Masaki [3 ]
机构
[1] Univ Seoul, Dept Mat Sci & Engn, Seoul 130743, South Korea
[2] Korea Inst Mat Sci, Engn Ceram Grp, Chang Won 641831, Gyeongnam, South Korea
[3] Osaka Prefecture Univ, Grad Sch Engn, Dept Mat Sci, Naka Ku, Osaka 5998531, Japan
关键词
SiC; Porosity; Strength; Porosity control; Polysiloxane; MICROSTRUCTURAL CHARACTERIZATION; CARBOTHERMAL REDUCTION; MECHANICAL-PROPERTIES; SIC CERAMICS; WOOD; INFILTRATION; FABRICATION; BEHAVIOR; CELL; CONVERSION;
D O I
10.1016/j.jeurceramsoc.2009.03.027
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Porous SiC ceramics were fabricated by the carbothermal reduction of polysiloxane-derived SiOC containing polymer microbeads followed by sintering. The effect of the SiC powder: polysiloxane-derived SiC (SiC:PDSiC) ratio on the porosity and flexural strength of the porous SiC ceramics were investigated. The porosity generally increased with decreasing SiC:PDSiC ratio when sintered at the same temperature. It was possible to control the porosity of porous SiC ceramics within a range of 32-64% by adjusting the sintering temperature and SiC:PDSiC ratio while keeping the sacrificial template content to 50 vol%. The flexural strengths generally decreased with increasing porosity at the same SiC:PDSiC ratio. However, a SiC:PDSiC ratio of 9:1 and a sintering temperature of 1750 degrees C resulted in excellent strength of 57 MPa at 50% porosity. Judicious selection of the sintering temperature and SiC:PDSiC ratio is an efficient way of controlling the porosity and strength of porous SiC ceramics. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2867 / 2872
页数:6
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