Two-dimensional hexagonal hydrogen-bonded network with triangle-like large cavities: hexakis(4-carboxyphenyl)benzene

被引：83

作者：

Kobayashi, K ^{[1
]}

Shirasaka, T

Horn, E

Furukawa, N

机构：

[1] Univ Tsukuba, Dept Chem, Tsukuba, Ibaraki, Japan

[2] Univ Tsukuba, Tsukuba Adv Res Alliance Ctr, Tsukuba, Ibaraki, Japan

[3] Rikkyo Univ, Dept Chem, Toshima Ku, Tokyo 1718501, Japan

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 01期

关键词：

carboxylic acids; carboxylic acid derivatives; hydrogen bonding; supramolecular chemistry; X-ray crystallography;

D O I：

10.1016/S0040-4039(99)02008-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Hexakis(4-carboxyphenyl)benzene (1) as a radially functionalized hexagonal host was synthesized by the Cocatalyzed cyclotrimerization of diarylacetylene. When recrystallized from MeOH, host 1 self-assembles into a two-dimensional hexagonal hydrogen-bonded network having triangle-like large cavities (one side of ca. 15.2 Angstrom), each of which is filled with guest molecules without interpenetration of the crystal lattice. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：89 / 93

页数：5

共 25 条

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