Supramolecular control of photochemical enantiomeric induction and radical pair recombination in zeolites

被引：18

作者：

Kaprinidis, NA ^{[1
]}

Landis, MS ^{[1
]}

Turro, NJ ^{[1
]}

机构：

[1] COLUMBIA UNIV,DEPT CHEM,NEW YORK,NY 10027

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 15期

关键词：

D O I：

10.1016/S0040-4039(97)00426-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Geminate radical pairs are formed from the alpha-photocleavage of aryl ketones within the supercage of zeolites which has been modified with chiral guest molecules. Herein, we report the supramolecular structure and dynamic control of both the enantiomeric selectivity and probability of the recombination of the radical pairs. (C) 1997 Elsevier Science Ltd.

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页码：2609 / 2612

页数：4

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