Synthesis, characterisation and catalytic activity of porous vanadyl phosphonate-modified silicas

被引：21

作者：

Jurado-Gonzalez, M ^{[1
]}

Ou, DL ^{[1
]}

Sullivan, AC ^{[1
]}

Wilson, JRH ^{[1
]}

机构：

[1] Univ London, Queen Mary, Dept Chem, London E1 4NS, England

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2002年 / 12卷 / 12期

关键词：

D O I：

10.1039/b207833c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 [物理化学]; 081704 [应用化学];

摘要：

Synthetic routes to porous ethylphosphonic acid-modified silicas with high T/Q ratios are described. The resulting materials were characterised using Si-29, P-31 and C-13 solid state NMR, nitrogen sorption porosimetry and elemental analysis. In addition, conditions for post-modification using [VO(SO4).5H(2)O] are described; the vanadyl derivatives were characterised by porosimetry, elemental analysis, EPR and UV-Vis spectroscopy. One of these vanadyl derivatives is a useful catalyst for the oxidation of cis-cyclooctene using aqueous hydrogen peroxide as the oxidant.

引用

页码：3605 / 3609

页数：5

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