Synthesis and structure of a helical polymer [Ag(R,R-DIOP)(NO3)](n) {DIOP=(4R,5R)-trans-4,5-bis[(diphenylphosphino)methyl]-2,2-dimethyl-1,3-dioxalane}

被引：52

作者：

Wu, B ^{[1
]}

Zhang, WJ ^{[1
]}

Yu, SY ^{[1
]}

Wu, XT ^{[1
]}

机构：

[1] CHINESE ACAD SCI,FUJIAN INST RES STRUCT MATTER,STATE KEY LAB STRUCT CHEM,FUZHOU 350002,FUJIAN,PEOPLES R CHINA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1997年 / 11期

关键词：

D O I：

10.1039/a700681k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A polymeric complex of silver(I) with the chiral ligand (R,R)-DIOP {DIOP = (4R,5R)-trans-4,5-bis[(diphenylphosphino)methyl]-2,2-dimethyl- 1,3-dioxalane} has been synthesized; its crystal structure revealed that the complex had a right-handed helical extended structure and consists of a silver atom co-ordinated by two phosphorus atoms of two adjacent (R,R)-DIOP ligands and an oxygen atom of nitrate.

引用

收藏

页码：1795 / 1796

页数：2

相关论文

共 17 条

[1] MULTICOMPONENT SELF-ASSEMBLY - SPONTANEOUS FORMATION OF A CYLINDRICAL COMPLEX FROM 5 LIGANDS AND 6 METAL-IONS [J].

BAXTER, P ;

LEHN, JM ;

DECIAN, A ;

FISCHER, J .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (01) :69-72

[2] SYNTHESIS AND X-RAY CHARACTERIZATION OF SOME HETEROMETALLIC HG-M COMPLEXES WITH 2-OXAZOLIDONE [J].

CARRAD, LH ;

GOODGAME, DML ;

HILL, SPW ;

WILLIAMS, DJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (07) :1003-1008

[3] ONE-DIMENSIONAL COORDINATION POLYMERS - APPLICATIONS TO MATERIAL SCIENCE [J].

CHEN, CT ;

SUSLICK, KS .

COORDINATION CHEMISTRY REVIEWS, 1993, 128 (1-2) :293-322

[4] SYNTHESIS AND X-RAY STRUCTURE OF A NOVEL CHIRAL TRINUCLEAR TITANIUM-TETRAOL COMPLEX [J].

COREY, EJ ;

CYWIN, CL ;

NOE, MC .

TETRAHEDRON LETTERS, 1994, 35 (01) :69-72

[5] CRYSTAL-STRUCTURES OF THE (-)-DIOP COMPLEXES OF NICKEL, PALLADIUM AND PLATINUM DICHLORIDE [J].

GRAMLICH, V ;

CONSIGLIO, G .

HELVETICA CHIMICA ACTA, 1979, 62 (04) :1016-1024

[6] PREPARATION AND STRUCTURAL CHARACTERIZATION OF [AG2(DPM)2(NO3)2] AND [AG4(DPM)4(NO3)2]2+[PF6]-2 - CONFORMATIONAL FLEXIBILITY IN THE M2P4 CORE STRUCTURE OF BIS(DIPHENYLPHOSPHINO)METHANE COMPLEXES [J].

HO, DM ;

BAU, R .

INORGANIC CHEMISTRY, 1983, 22 (26) :4073-4079

[7] PERSPECTIVES IN SUPRAMOLECULAR CHEMISTRY - FROM MOLECULAR RECOGNITION TOWARDS MOLECULAR INFORMATION-PROCESSING AND SELF-ORGANIZATION [J].

LEHN, JM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (11) :1304-1319

[8] CHIRAL HELICAL LEWIS-ACIDS FOR ASYMMETRIC DIELS-ALDER CATALYSTS [J].

MARUOKA, K ;

MURASE, N ;

YAMAMOTO, H .

JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (11) :2938-2939

[9]

MURRER BA, 1979, SYNTHESIS-STUTTGART, P350

[10]

SHELDRICK G, 1993, SHELXL 93