Nitride and carbide of molybdenum and tungsten as substitutes of iridium for the catalysts used for space communication

被引:56
作者
Rodrigues, JAJ
Cruz, GM
Bugli, G
Boudart, M
DjegaMariadassou, G
机构
[1] INST NACL PESQUISAS ESPACIAIS,BR-12630000 CACHOEIRA PAU,SP,BRAZIL
[2] FAC ENGN QUIM LORENA,BR-12600000 LORENA,SP,BRAZIL
[3] STANFORD UNIV,STANFORD,CA 94305
关键词
catalytic decomposition of hydrazine; MoNxOy catalyst; WCxOy catalyst;
D O I
10.1023/A:1019059410876
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Satellites are equipped with microthrusters that control their orbit and attitude. The thrust is achieved by the catalytic decomposition of hydrazine by iridium supported on alumina. As nitrides and carbides of molybdenum and tungsten behave like noble metals in many catalytic reactions, they were tried in a 2 newton hydrazine microthruster. Their performance was similar to that of the iridium catalyst, with respect to ignition delay and thrust. Their mechanical resistance appears higher than that of iridium-based catalyst. This application is the first practical one for nitrides and carbides of early transition metals as substitutes of noble metals, a possibility first reported in 1973.
引用
收藏
页码:1 / 3
页数:3
相关论文
共 17 条
[1]   CATALYTIC HYDROTREATING OF INDOLE, BENZOTHIOPHENE, AND BENZOFURAN OVER MO2N [J].
ABE, H ;
BELL, AT .
CATALYSIS LETTERS, 1993, 18 (1-2) :1-8
[2]  
Boudart M, 1980, P 7 INT C CAT, V1, P578
[3]   SYNTHESIS AND CHARACTERIZATION OF MOLYBDENUM NITRIDE HYDRODENITROGENATION CATALYSTS [J].
CHOI, JG ;
BRENNER, JR ;
COLLING, CW ;
DEMCZYK, BG ;
DUNNING, JL ;
THOMPSON, LT .
CATALYSIS TODAY, 1992, 15 (02) :201-222
[4]   CHARACTERIZATION OF CO ADSORBED ON gamma-Mo2N BY NMR SPECTROSCOPY [J].
Haddix, Grant W. ;
Bell, Alexis T. ;
Reimer, Jeffrey A. .
CATALYSIS LETTERS, 1988, 1 (6-7) :207-212
[5]   SYNTHESIS, CHARACTERIZATION, AND CATALYTIC PROPERTIES OF CLEAN AND OXYGEN-MODIFIED TUNGSTEN CARBIDES [J].
IGLESIA, E ;
RIBEIRO, FH ;
BOUDART, M ;
BAUMGARTNER, JE .
CATALYSIS TODAY, 1992, 15 (02) :307-337
[6]   REACTIVITY OF TUNGSTEN CARBIDES .1. CATALYTIC AND TEMPERATURE-PROGRAMMED REACTIONS OF METHANOL [J].
LEE, JS ;
BOUDART, M .
CATALYSIS LETTERS, 1991, 8 (2-4) :107-114
[7]   PLATINUM-LIKE BEHAVIOR OF TUNGSTEN CARBIDE IN SURFACE CATALYSIS [J].
LEVY, RB ;
BOUDART, M .
SCIENCE, 1973, 181 (4099) :547-549
[8]  
MAZULEVSKII EA, 1977, KINET KATAL, V18, P767
[9]  
Oyama S. T., 1980, J RES I CAT HOKKAIDO, V28, P305
[10]  
OYAMA ST, 1992, J SOLID STATE CHEM, V96, P442, DOI 10.1016/S0022-4596(05)80279-8