Kinetics and dynamics in the photodissociation of the allyl radical

被引：40

作者：

Deyerl, HJ ^{[1
]}

Gilbert, T ^{[1
]}

Fischer, I ^{[1
]}

Chen, P ^{[1
]}

机构：

[1] ETH ZURICH, ORGAN CHEM LAB, CH-8092 ZURICH, SWITZERLAND

来源：

JOURNAL OF CHEMICAL PHYSICS | 1997年 / 107卷 / 08期

关键词：

D O I：

10.1063/1.474704

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The direct observation of the products, kinetics and translational energy release from the photodissociation of the allyl radical, C3H5, upon excitation in the near-uv is reported. A statistical analysis of the data shows that they are in agreement with allene formation being the dominant H-loss reaction channel. (C) 1997 American Institute of Physics.

引用

页码：3329 / 3332

页数：4

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