Linear recognition of dicarboxylates by ditopic macrocyclic complexes

被引:41
作者
Boiocchi, Massimo
Bonizzoni, Marco
Moletti, Alberto
Pasini, Dario
Taglietti, Angelo
机构
[1] Univ Pavia, Dept Organ Chem, Pavia, Italy
[2] Univ Pavia, Ctr Grandi Strumenti, Pavia, Italy
[3] Univ Pavia, Dept Gen Chem, Pavia, Italy
关键词
D O I
10.1039/b616492g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new macrocyclic ligand, whose dicopper complex acts as a receptor for dianions in water at physiological pH, was prepared, and comparison with a structurally isomeric but larger complex demonstrates that the selectivity pattern for dicarboxylate binding obeys the principles of preorganization and linear recognition.
引用
收藏
页码:352 / 356
页数:5
相关论文
共 23 条
[1]   SIR97:: a new tool for crystal structure determination and refinement [J].
Altomare, A ;
Burla, MC ;
Camalli, M ;
Cascarano, GL ;
Giacovazzo, C ;
Guagliardi, A ;
Moliterni, AGG ;
Polidori, G ;
Spagna, R .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1999, 32 :115-119
[2]   Some guidelines for the design of anion receptors [J].
Amendola, Valeria ;
Bonizzoni, Marco ;
Esteban-Gomez, David ;
Fabbrizzi, Luigi ;
Licchelli, Maurizio ;
Sancenon, Felix ;
Taglietti, Angelo .
COORDINATION CHEMISTRY REVIEWS, 2006, 250 (11-12) :1451-1470
[3]  
ARTZ SP, 1984, J AM CHEM SOC, V106, P2160, DOI 10.1021/ja00319a042
[4]  
Asakawa M, 1997, CHEM-EUR J, V3, P463
[5]   A dimetallic cage with a long ellipsoidal cavity for the fluorescent detection of dicarboxylate anions in water [J].
Boiocchi, M ;
Bonizzoni, M ;
Fabbrizzi, L ;
Piovani, G ;
Taglietti, A .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (29) :3847-3852
[6]  
Broker, 2003, SAINT SOFTW REF MAN
[7]   THE SYNTHESIS OF NEW BINUCLEATING POLYAZA MACROCYCLIC AND MACROBICYCLIC LIGANDS - DIOXYGEN AFFINITIES OF THE COBALT COMPLEXES [J].
CHEN, D ;
MARTELL, AE .
TETRAHEDRON, 1991, 47 (34) :6895-6902
[8]   The design of fluorescent sensors for anions: taking profit from the metal-ligand interaction and exploiting two distinct paradigms [J].
Fabbrizzi, L ;
Licchelli, M ;
Taglietti, A .
DALTON TRANSACTIONS, 2003, (18) :3471-3479
[9]   Investigation of equilibria in solution. Determination of equilibrium constants with the HYPERQUAD suite of programs [J].
Gans, P ;
Sabatini, A ;
Vacca, A .
TALANTA, 1996, 43 (10) :1739-1753
[10]   Catalytic alternative of the Ullmann reaction [J].
Hassan, J ;
Penalva, V ;
Lavenot, L ;
Gozzi, C ;
Lemaire, M .
TETRAHEDRON, 1998, 54 (45) :13793-13804