A new luminol chemiluminescence reaction using a tetravalent nickel-periodate complex as the oxidant

被引：33

作者：

Yang, Chunyan ^{[1
]}

Zhang, Zhujun ^{[1
]}

Wang, Jinli ^{[1
]}

机构：

[1] Shaanxi Normal Univ, Coll Chem & Mat Sci, Xian 710062, Peoples R China

来源：

MICROCHIMICA ACTA | 2009年 / 167卷 / 1-2期

关键词：

Chemiluminescence; Luminol; Diperiodatonickelate; Isoniazid; FLOW-INJECTION CHEMILUMINESCENCE; HYDROGEN-PEROXIDE;

D O I：

10.1007/s00604-009-0223-6

中图分类号：

O65 [分析化学];

学科分类号：

070302 [分析化学];

摘要：

We report on a new chemiluminescence (CL) reaction that occurs between luminol and di-periodatonickelate in alkaline medium. The possible mechanism of this system is discussed based on the kinetics of the reaction, its CL and UV spectra. The system exhibits a sensitivity that is higher than any other system based on luminol. It was successfully applied to the determination of isoniazid in serum.

引用

页码：91 / 96

页数：6

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