Bioinspired Synthesis of CaCO3 Superstructures through a Novel Hydrogel Composite Membranes Mineralization Platform: A Comprehensive View

被引：37

作者：

Di Profio, Gianluca ^{[1
]}

Salehi, Shabnam Majidi ^{[1
,2
]}

Caliandro, Rocco ^{[3
]}

Guccione, Pietro ^{[4
]}

Nico, Giovanni ^{[5
]}

Curcio, Efrem ^{[2
]}

Fontananova, Enrica ^{[1
]}

机构：

[1] CNR, Natl Res Council Italy, Inst Membrane Technol ITM, Via P Bucci Univ Calabria,Cubo 17-C, I-87036 Arcavacata Di Rende, CS, Italy

[2] Univ Calabria, Dept Environm & Chem Engn DIATIC, UNICAL, Via P Bucci Cubo 45-A, I-87036 Arcavacata Di Rende, CS, Italy

[3] CNR, Inst Crystallog, Natl Res Council Italy, Via G Amendola 122-O, I-70126 Bari, BA, Italy

[4] Polytech Bari, Dept Elect & Informat Engn DEI, Via G Orabona 4, I-70125 Bari, BA, Italy

[5] CNR, Natl Res Council Italy, Inst Calculus Applicat Mauro Picone IAC, Via G Amendola 122-O, I-70126 Bari, BA, Italy

来源：

ADVANCED MATERIALS | 2016年 / 28卷 / 04期

关键词：

AMORPHOUS CALCIUM-CARBONATE; RAMAN-SPECTROSCOPY; SINGLE-CRYSTALS; SURFACE-STRUCTURE; ARTIFICIAL NACRE; GROWTH; CRYSTALLIZATION; BIOMINERALIZATION; MORPHOLOGIES; SPHERULITES;

D O I：

10.1002/adma.201504608

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

Hydrogel composite membranes (HCMs) are used as novel mineralization platforms for the bioinspired synthesis of CaCO3 superstructures. A comprehensive statistical analysis of the experimental results reveals quantitative relationships between crystallization conditions and crystal texture and a strong selectivity toward complex morphologies when monomers bearing carboxyl and hydroxyl groups are used together in the hydrogel layer synthesis in HCMs. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：610 / 616

页数：7

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