Facile approach to prepare loose-packed cobalt hydroxide nano-flakes materials for electrochemical capacitors

被引:250
作者
Kong, Ling-Bin [1 ,2 ]
Lang, Jun-Wei [1 ]
Liu, Min [1 ]
Luo, Yong-Chun [2 ]
Kang, Long [2 ]
机构
[1] Lanzhou Univ Technol, State Key Lab Gansu Adv Nonferrous Met Mat, Lanzhou 730050, Peoples R China
[2] Lanzhou Univ Technol, Minist Educ, Key Lab Nonferrous Met Alloys & Proc, Lanzhou 730050, Peoples R China
基金
中国国家自然科学基金;
关键词
Electrochemical capacitors; Cobalt hydroxide; Specific capacitance; Nano-flakes; Pseudo-capacitance; ELECTRODE MATERIAL; NICKEL-OXIDE; FILM; SUPERCAPACITORS; POLYANILINE; MNO2;
D O I
10.1016/j.jpowsour.2009.06.016
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Cobalt hydroxide nano-flakes are successfully synthesized by a facile chemical precipitation method. Electrochemical characterization is performed using cyclic voltammetry. chronopotentiometry and impedance spectroscopy, respectively. These cobalt hydroxide nano-flakes maintain high utilization at high rates of discharge. A maximum specific capacitance of 735 Fg(-1) can be achieved in 2 M aqueous KOH with the potential range from -0.2 to 0.4V (vs. SCE) in a half-cell setup configuration for the nano-flakes Co(OH)(2) electrode, suggesting its potential application in electrochemical capacitors. Furthermore, the effect of annealing temperatures on the electrochemical capacitance characteristics is also been systematically explored. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:1194 / 1201
页数:8
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