Copolymerization of carbon dioxide and epoxide

被引：348

作者：

Sugimoto, H ^{[1
]}

Inoue, S ^{[1
]}

机构：

[1] Tokyo Univ Sci, Dept Ind Chem, Fac Engn, Tokyo 1628601, Japan

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2004年 / 42卷 / 22期

关键词：

alternating copolymerization; polycarbonate; carbon dioxide; epoxide; anionic polymerization; copolymerization;

D O I：

10.1002/pola.20319

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The alternating copolymerization of carbon dioxide and epoxide to produce polycarbonate has attracted the attention of many chemists because it is one of the most promising methodologies for the utilization of carbon dioxide as a safe, clean, and abundant raw material in synthetic chemistry. Recent development of catalysts for alternating copolymerization is based on the rational design of metal complexes, particularly complexes of transition metals with well-defined structures. In this article, the history and recent successful examples of the alternating copolymerization of carbon dioxide and epoxide are described. (C) 2004 Wiley Periodicals, Inc.

引用

页码：5561 / 5573

页数：13

共 77 条

[1] ALTERNATING COPOLYMERIZATION OF CARBON-DIOXIDE AND EPOXIDE CATALYZED BY THE ALUMINUM PORPHYRIN-QUATERNARY ORGANIC SALT OR TRIPHENYLPHOSPHINE SYSTEM - SYNTHESIS OF POLYCARBONATE WITH WELL-CONTROLLED MOLECULAR-WEIGHT [J].

AIDA, T ;

ISHIKAWA, M ;

INOUE, S .

MACROMOLECULES, 1986, 19 (01) :8-13

[2] High-activity, single-site catalysts for the alternating copolymerization of CO2 and propylene oxide [J].

Allen, SD ;

Moore, DR ;

Lobkovsky, EB ;

Coates, GW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (48) :14284-14285

[3] NEW CATALYTIC-SYSTEMS FOR THE FIXATION OF CARBON-DIOXIDE .1. COPOLYMERIZATION OF CO2 AND PROPYLENE-OXIDE WITH NEW RARE-EARTH CATALYSTS-RE(P204)3-AL(I-BU)3-R(OH)N [J].

CHEN, XH ;

SHEN, ZQ ;

ZHANG, YF .

MACROMOLECULES, 1991, 24 (19) :5305-5308

[4] Single-site β-diiminate zinc catalysts for the alternating copolymerization of CO2 and epoxides:: Catalyst synthesis and unprecedented polymerization activity [J].

Cheng, M ;

Moore, DR ;

Reczek, JJ ;

Chamberlain, BM ;

Lobkovsky, EB ;

Coates, GW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (36) :8738-8749

[5] Enantiomerically-enriched organic reagents via polymer synthesis:: enantioselective copolymerization of cycloalkene oxides and CO2 using homogeneous, zinc-based catalysts [J].

Cheng, M ;

Darling, NA ;

Lobkovsky, EB ;

Coates, GW .

CHEMICAL COMMUNICATIONS, 2000, (20) :2007-2008

[6] Catalytic reactions involving C1 feedstocks:: New high-activity Zn(II)-based catalysts for the alternating copolymerization of carbon dioxide and epoxides [J].

Cheng, M ;

Lobkovsky, EB ;

Coates, GW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (42) :11018-11019

[7] Three-coordinate zinc amide and phenoxide complexes supported by a bulky Schiff base ligand [J].

Chisholm, MH ;

Gallucci, JC ;

Zhen, HH ;

Huffman, JC .

INORGANIC CHEMISTRY, 2001, 40 (19) :5051-+

[8] Mechanistic aspects of the copolymerization of CO2 and epoxides by soluble zinc bis(phenoxide) catalysts as revealed by their cadmium analogues [J].

Darensbourg, DJ ;

Niezgoda, SA ;

Draper, JD ;

Reibenspies, JH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (19) :4690-4698

[9] SYNTHESES AND STRUCTURES OF EPOXIDE ADDUCTS OF SOLUBLE CADMIUM(II) CARBOXYLATES - MODELS FOR THE INITIATION PROCESS IN EPOXIDE CO2 COUPLING REACTIONS [J].

DARENSBOURG, DJ ;

HOLTCAMP, MW ;

KHANDELWAL, B ;

KLAUSMEYER, KK ;

REIBENSPIES, JH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (01) :538-539

[10] (Salen)CrIIIX catalysts for the copolymerization of carbon dioxide and epoxides:: Role of the initiator and cocatalyst [J].

Darensbourg, DJ ;

Mackiewicz, RM ;

Rodgers, JL ;

Phelps, AL .

INORGANIC CHEMISTRY, 2004, 43 (06) :1831-1833

← 1 2 3 4 5 6 7 8 →