Radical reactions catalysed by ruthenium(II) complexes with anionic carborane phosphine ligands:: Kharasch addition to olefins and controlled polymerisation

被引：54

作者：

Simal, F

Sebille, S

Demonceau, A

Noels, AF

Nuñez, R

Abad, M

Teixidor, F

Viñas, C

机构：

[1] Univ Liege, Macromol Chem & Organ Catalysis Lab, B-4000 Liege, Belgium

[2] CSIC, Inst Ciencia Mat Barcelona, E-08193 Barcelona, Spain

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 28期

关键词：

carboranes; catalysis; olefins; polymerisation; radicals and radical reactions; ruthenium and compounds;

D O I：

10.1016/S0040-4039(00)00840-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ruthenium-carborane complexes 1-3 mediated the Kharasch addition of carbon tetrachloride across olefins with high yields which markedly depended on the catalyst and the substrate used. In addition, the atom transfer radical polymerisation of methyl methacrylate could be carried out in a highly controlled way. (C) 2000 Elsevier Science Ltd All rights reserved.

引用

页码：5347 / 5351

页数：5

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2-L

[3]

BARATTA W, 1999, ANGEW CHEM, V111, P1733

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