Experimentally Determined Redox Potentials of Individual (n,m) Single-Walled Carbon Nanotubes

被引:145
作者
Tanaka, Yasuhiko [1 ]
Hirana, Yasuhiko [1 ]
Niidome, Yasuro [1 ]
Kato, Koichiro [3 ]
Saito, Susumu [3 ]
Nakashima, Naotoshi [1 ,2 ]
机构
[1] Kyushu Univ, Grad Sch Engn, Dept Appl Chem, Fukuoka 8190395, Japan
[2] Japan Sci & Technol CREST, Chiyoda Ku, Tokyo 1020075, Japan
[3] Tokyo Inst Technol, Dept Phys, Meguro Ku, Tokyo 152, Japan
关键词
electrochemistry; nanotubes; photoluminescence; redox chemistry; IN-SITU RAMAN; ELECTRONIC-STRUCTURE; CHARGE-TRANSFER; FLUORESCENCE; SPECTRA; NIR;
D O I
10.1002/anie.200902468
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nanotubes reveal their potential: The fabrication of a thin film that retains isolated singlewalled nanotubes (SWNTs) allows the experimental determination of the redox potentials of many individual SWNTs that have different chirality indexes (n,m). The method is simple and applicable to all individual SWNTs whose near-IR photoluminescence (PL) is detectable (see picture). © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:7655 / 7659
页数:5
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