Synthesis, structural characterization, and fluorescent chemosensory properties of novel molecular clips based on diethoxycarbonyl glycoluril

被引:50
作者
Hu, Sheng-Li
She, Neng-Fang
Yin, Guo-Dong
Guo, Hui-Zhen
Wu, An-Xin
Yang, Chu-Luo [1 ]
机构
[1] Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China
[2] Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China
基金
中国国家自然科学基金;
关键词
diethoxycarbonyl glycoluril; molecular clip; Fe(III); fluorescent chemosensor;
D O I
10.1016/j.tetlet.2006.12.138
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A pair of novel fluorescent molecular clips was synthesized from diethoxycarbonal glycoluril cyclic ether and 1,2-dihydroindazol-3-one. Their structures and conformations were confirmed by single crystal X-ray diffraction and chemosensory properties were studied by fluorescent spectroscope. Both of them exhibited selective recognition toward Fe3+ over other metal ions examined in DMF/CH3OH (50:1, v/v). (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1591 / 1594
页数:4
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