Mild and efficient aryl-alkenyl coupling via Pd(II) catalysis in the presence of oxygen or Cu(II) oxidants

被引：74

作者：

Parrish, JP ^{[1
]}

Jung, YC ^{[1
]}

Shin, SI ^{[1
]}

Jung, KW ^{[1
]}

机构：

[1] Univ S Florida, Dept Chem, Tampa, FL 33620 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2002年 / 67卷 / 20期

关键词：

D O I：

10.1021/jo020159p

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We report herein a mild and efficient method for carbon-carbon bond formation between aryl stannanes and olefins via Pd(II) catalysis in the presence of oxygen or Cu(II) oxidants as a reoxidant. The process allows reactions between various olefins and aryl stannanes of varying electron density. Coupling methods under these oxidation conditions are comparatively described, and the benefits and limitations are also discussed.

引用

页码：7127 / 7130

页数：4

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