Benzobisthiazole-Thiophene Copolymer Semiconductors: Synthesis, Enhanced Stability, Field-Effect Transistors, and Efficient Solar Cells

被引：105

作者：

Ahmed, Eilaf

Kim, Felix S.

Xin, Hao

Jenekhe, Samson A. ^{[1
]}

机构：

[1] Univ Washington, Dept Chem Engn, Seattle, WA 98195 USA

来源：

MACROMOLECULES | 2009年 / 42卷 / 22期

关键词：

EFFECT CARRIER MOBILITY; NONLINEAR OPTICAL-PROPERTIES; CHARGE-TRANSPORT; BUILDING-BLOCKS; POLYMERS; PERFORMANCE; POLY(3-ALKYLTHIOPHENES); MORPHOLOGY; BLENDS; ELECTROCHEMISTRY;

D O I：

10.1021/ma9015278

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis and characterization of a new organic solvent soluble benzobisthiazole-thiophene copolymer based on alternating benzobisthiazole and oligo-3-octylthiophene units in the backbone, poly (benzobisthiazole-alt-3- octylquarterthiophene) (PBTOT) has been demonstrated. Differential scanning calorimetry (DSC) showed a melting peak (Tm) at 367 °C and recrystallization (TO) at 356 °C for PBTOT-2 and slightly lowers melting transition for PBTOT-1. The π-conjugated polymer semiconductors are of broad interest for applications in organic electronics and optoelectronics including field-effect transistors and photovoltaic cells. The enhanced interchain interactions in PBTOT include the much higher melt transition temperature and improved field-effect charge transport compared to P3OT.

引用

页码：8615 / 8618

页数：4

共 46 条

[1] The influence of the optoelectronic properties of poly(3-alkylthiophenes) on the device parameters in flexible polymer solar cells [J].