n-type building blocks for organic electronics: A homologous family of fluorocarbon-substituted thiophene oligomers with high carrier mobility

被引：303

作者：

Facchetti, A

Mushrush, M

Katz, HE

Marks, TJ

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

[2] Northwestern Univ, Ctr Mat Res, Evanston, IL 60208 USA

[3] Bell Labs, Lucent Technol, Murray Hill, NJ 07974 USA

来源：

ADVANCED MATERIALS | 2003年 / 15卷 / 01期

关键词：

D O I：

10.1002/adma.200390003

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A substantial enhancement of thermal stability, volatility, and electron affinity, switching the semiconducting behavior from p- to n-type, is achieved by fluoroalkyl substitution of thiophene oligomers (see Figure). When this novel series is compared with the fluorine-free analogues, trends in molecular packing, optical absorption, HOMO-LUMO gap, and pi-pi interactions are found to be strikingly similar.

引用

页码：33 / +

页数：7

共 52 条

[1] FIELD-EFFECT TRANSISTORS USING ALKYL SUBSTITUTED OLIGOTHIOPHENES
AKIMICHI, H
WARAGAI, K
HOTTA, S
KANO, H
SAKAKI, H
[J]. APPLIED PHYSICS LETTERS, 1991, 58 (14) : 1500 - 1502
[2] [Anonymous], 1997, Handbook of Organic Conductive Molecules and Polymers
[3] [Anonymous], 1998, ELECT MAT OLIGOMER A
[4] Soluble and processable regioregular poly(3-hexylthiophene) for thin film field-effect transistor applications with high mobility
Bao, Z
Dodabalapur, A
Lovinger, AJ
[J]. APPLIED PHYSICS LETTERS, 1996, 69 (26) : 4108 - 4110
[5] New air-stable n-channel organic thin film transistors
Bao, ZA
Lovinger, AJ
Brown, J
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (01) : 207 - 208
[6] Oligothiophene S,S-dioxides.: Synthesis and electronic properties in relation to the parent oligothiophenes
Barbarella, G
Favaretto, L
Sotgiu, G
Zambianchi, M
Antolini, L
Pudova, O
Bongini, A
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (16) : 5497 - 5506
[7] Solid-state conformation, molecular packing, and electrical and optical properties of processable β-methylated sexithiophenes
Barbarella, G
Zambianchi, M
Antolini, L
Ostoja, P
Maccagnani, P
Bongini, A
Marseglia, EA
Tedesco, E
Gigli, G
Cingolani, R
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (38) : 8920 - 8926
[8] Bard A.J., 1983, Surface Technology, V20, P91, DOI DOI 10.1016/0376-4583(83)90080-8
[9] BAUERLE P, 1999, SYNTHESIS OLIGOTHIOP
[10] ORGANIC N-TYPE FIELD-EFFECT TRANSISTOR
BROWN, AR
DELEEUW, DM
LOUS, EJ
HAVINGA, EE
[J]. SYNTHETIC METALS, 1994, 66 (03) : 257 - 261

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