Oligomerization chemistry of a metallabenzene cycloadduct. Synthesis and structure of an organometallic crown compound

被引:13
作者
Bleeke, JR
Behm, R
Beatty, AM
机构
[1] Department of Chemistry, Washington University, St. Louis
关键词
D O I
10.1021/om961070a
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The CS2 adduct of ''iridabenzene'' undergoes dimerization and cyclotrimerization reactions by linking subunits through thiocarbonyl sulfur centers. The cyclotrimerization product (compound 4) has been structurally characterized and contains a novel organometallic trithia-12-crown-3 ring system.
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页码:1103 / 1105
页数:3
相关论文
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