Langmuir-Blodgett films of a thermally labile 1:1 adduct of C-60 fullerene and 8-(9-anthryl)-7-oxaoctanoic acid

被引：26

作者：

Kawai, T ^{[1
]}

Scheib, S ^{[1
]}

Cava, MP ^{[1
]}

Metzger, RM ^{[1
]}

机构：

[1] UNIV ALABAMA,DEPT CHEM,TUSCALOOSA,AL 35487

来源：

LANGMUIR | 1997年 / 13卷 / 21期

关键词：

D O I：

10.1021/la9701945

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel amphiphilic C-60 derivative, C-60-AOOA, was prepared for Langmuir-Blodgett (LB) films by a thermally reversible Diels-Alder reaction of C-60 and an anthracene derivative with a carboxylic acid group side chain. This derivative showed a limiting surface area per molecule (at zero pressure) as large as 0.92 nm(2), which is reasonable for a true Langmuir monolayer of a C-60 derivative. LB films were formed on various substrates. Their structure and thermal behavior were studied by X-ray diffraction and FT-IR: the transferred C-60-AOOA decomposes upon heat treatment, to form a C-60 layer and/or C-60/C-60-AOOA mixed layers.

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收藏

页码：5627 / 5633

页数：7

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