Switching stereocontrol in the high pressure-induced hetero-Diels-Alder reaction

被引：17

作者：

Al-Badri, H

Collignon, N

Maddaluno, J ^{[1
]}

Masson, S

机构：

[1] Univ Rouen, IRCOF, Lab Fonct Azotees & Oxygenees Complexes, CNRS,UPRES A 6014, F-76821 Mont St Aignan, France

[2] INSA Rouen, IRCOF, Lab Heterochim Organ, CNR,UPRES A 6014, F-76131 Mont St Aignan, France

[3] Univ Caen, Lab Chim Mol & Thioorgan, CNRS, UMR 6507, F-14050 Caen, France

[4] ISMRA Univ Caen, F-14050 Caen, France

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 13期

关键词：

D O I：

10.1039/b003060k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The formation of a transient Michael adduct, triggering an in-situ isomerization of the heterodiene, is postulated to explain the reversal of the diastereoselectivity of high pressure-promoted hetero-Diels-Alder reactions carried out in the presence of pyridine.

引用

页码：1191 / 1192

页数：2

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