Hole mobility in DNA A tracts

被引：74

作者：

Lewis, Frederick D. ^{[1
]}

Zhu, Huihe ^{[1
]}

Daublain, Pierre ^{[1
]}

Cohen, Boiko ^{[1
]}

Wasielewski, Michael R. ^{[1
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 47期

关键词：

DNA conjugates; electron transfer; hole hopping; hole injection; hole trapping;

D O I：

10.1002/anie.200603455

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Whole scheme of things: The kinetics and efficiency of photoinduced hole transport across DNA A tracts with 1-7 base pairs have been determined from femtosecond transient absorption spectroscopic data. These values are strongly distance dependent over the first four base pairs, but are relatively insensitive to distance at longer distances. These kinetic results (□, ■) parallel the DNA-strand-cleavage results of Giese et al. (○, Black circle). (Graph Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7982 / 7985

页数：4

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