Functionalization of multi-walled carbon nanotubes with furan and maleimide compounds through Diels-Alder cycloaddition

被引：87

作者：

Chang, Chia-Ming ^{[1
]}

Liu, Ying-Ling ^{[1
]}

机构：

[1] Chung Yuan Christian Univ, Dept Chem Engn, Chungli 32023, Taoyuan, Taiwan

来源：

CARBON | 2009年 / 47卷 / 13期

关键词：

CROSS-LINKED POLYAMIDES; COVALENT FUNCTIONALIZATION; SIDEWALL FUNCTIONALIZATION; SUPRAMOLECULAR COMPLEXES; SURFACE; C-60; CHEMISTRY;

D O I：

10.1016/j.carbon.2009.06.058

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Functionalization of multi-walled carbon nanotubes (MWCNTs) is performed through Diels-Alder (DA) reaction, using either furfuryl alcohol (a diene) or N-(4-hydroxyphenyl)maleimide (NHMI, a dienophile) as a functionalization agent. The structures of the functionalized MWCNTs are characterized with Fourier-transform infrared spectroscopy and Raman spectroscopy. Thermogravimetric analysis results also demonstrate the presence of organic portions of the functionalized MWCNTs. The DA reaction is further applied to incorporate polymer chains onto MWCNT surfaces, using a polyamide with maleimide pendent groups. Transmission electron microscopy images show the presence of a polymer layer of about 2-5 nm around the polymer modified MWCNTs. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：3041 / 3049

页数：9

共 41 条

[1] Nanotubes from carbon [J].

Ajayan, PM .

CHEMICAL REVIEWS, 1999, 99 (07) :1787-1799

[2] Covalent surface chemistry of single-walled carbon nanotubes [J].

Banerjee, S ;

Hemraj-Benny, T ;

Wong, SS .

ADVANCED MATERIALS, 2005, 17 (01) :17-29

[3] Microwave-induced multiple functionalization of carbon nanotubes [J].

Brunetti, Fulvio G. ;

Herrero, M. Antonia ;

Munoz, Juan de M. ;

Diaz-Ortiz, Angel ;

Alfonsi, Jessica ;

Meneghetti, Moreno ;

Prato, Maurizio ;

Vazquez, Ester .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (25) :8094-8100

[4] A thermally re-mendable cross-linked polymeric material [J].

Chen, XX ;

Dam, MA ;

Ono, K ;

Mal, A ;

Shen, HB ;

Nutt, SR ;

Sheran, K ;

Wudl, F .

SCIENCE, 2002, 295 (5560) :1698-1702

[5] Soluble, discrete supramolecular complexes of single-walled carbon nanotubes with fluorene-based conjugated polymers [J].

Cheng, Fuyong ;

Imin, Patigul ;

Maunders, Christian ;

Botton, Gianluigi ;

Adronov, Alex .

MACROMOLECULES, 2008, 41 (07) :2304-2308

[6] Thermoresponsive, optically active films based on Diels-Alder chemistry [J].

Costanzo, Philip J. ;

Beyer, Frederick L. .

CHEMISTRY OF MATERIALS, 2007, 19 (25) :6168-6173

[7] Microwave-assisted sidewall functionalization of single-wall carbon nanotubes by Diels-Alder cycloaddition [J].

Delgado, JL ;

de la Cruz, P ;

Langa, F ;

Urbina, A ;

Casado, J ;

Navarrete, JTL .

CHEMICAL COMMUNICATIONS, 2004, (15) :1734-1735

[8] REVERSIBLE COVALENT ATTACHMENT OF C-60 TO A POLYMER SUPPORT [J].

GUHR, KI ;

GREAVES, MD ;

ROTELLO, VM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (13) :5997-5998

[9]

Hirsch A, 2002, ANGEW CHEM INT EDIT, V41, P1853, DOI 10.1002/1521-3773(20020603)41:11<1853::AID-ANIE1853>3.0.CO

[10]

2-N

← 1 2 3 4 5 →