A modular approach to trans-chelating, N-heterocyclic carbene ligand complexes

被引：85

作者：

Perry, MC ^{[1
]}

Cui, XH ^{[1
]}

Burgess, K ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77841 USA

来源：

TETRAHEDRON-ASYMMETRY | 2002年 / 13卷 / 18期

关键词：

D O I：

10.1016/S0957-4166(02)00535-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The N-methyl bis-imidazolium salts 3 were converted to the silver carbenes 7, then reacted to give palladium(II) complexes 4 with trans-chelating, bidentate bis-imidazolylidine ligands. The similar salts 8, that do not have N-methyl substituents, gave the tetradentate complexes 9 in direct reactions with palladium chloride. The potential of these complexes for asymmetric catalysis is discussed. (C) 2002 Published by Elsevier Science Ltd.

引用

页码：1969 / 1972

页数：4

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