What is the coordination number of copper(II) in metallosupramolecular chemistry?

被引：45

作者：

Chaurin, Valerie ^{[1
]}

Constable, Edwin C. ^{[1
]}

Housecroft, Catherine E. ^{[1
]}

机构：

[1] Univ Basel, Dept Chem, CH-4056 Basel, Switzerland

来源：

NEW JOURNAL OF CHEMISTRY | 2006年 / 30卷 / 12期

关键词：

D O I：

10.1039/b610306e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Analysis of structural and solution data shows a specific stabilisation of copper(II) in ternary complexes containing one 2,2:6',2"-terpyridine and one 2,2'-bipyridine ligand. This is not a general phenomenon relating to five-coordinate copper(II), but rather a specific consequence of the two ligand donor sets. The consequences of this observation for metallosupramolecular chemistry are discussed.

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页码：1740 / 1744

页数：5

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