Electrophilic platinum complexes: Catalytic reductive elimination of ethane from a tetramethylplatinum(IV) complex

被引：36

作者：

Hill, GS ^{[1
]}

Puddephatt, RJ ^{[1
]}

机构：

[1] UNIV WESTERN ONTARIO,DEPT CHEM,LONDON,ON N6A 5B7,CANADA

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 21期

关键词：

D O I：

10.1021/om970741h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reductive elimination of ethane from the thermally stable complex [PtMe4(dppe)] (dppe = Ph-2-PCH2CH2PPh2) is catalyzed by electrophiles such as [PtMe(O3SCF3)(dppe)] by a mechanism involving methyl group abstraction to give [PtMe3(dppe)](+), reductive elimination to give ethane and [PtMe(dppe)](+), and then methyl group return. to give [PtMe2(dppe)]. The reactions give insight into potential C-C bond activation mechanisms.

引用

页码：4522 / 4524

页数：3

共 12 条

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