Lithium bistrifluoromethanesulfonimidate-mediated regioselective ring opening of aziridines by amines

被引：23

作者：

Cossy, J

Bellosta, V

Alauze, V

Desmurs, JR

机构：

[1] ESPCI, Chim Organ Lab, F-75231 Paris 05, France

[2] ESPCI, CNRS, F-75231 Paris, France

[3] Rhodia, F-69457 Lyon 06, France

来源：

SYNTHESIS-STUTTGART | 2002年 / 15期

关键词：

aziridines; amines; ring opening; lithium bistrifluoromethanesulfonimidate; 1,2-diamines;

D O I：

10.1055/s-2002-34842

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the presence of a catalytic amount of LiNTf2 as a new promoter, a variety of N-substituted aziridines undergo ring opening by amines to afford the corresponding 1,2-diamino compounds, in high yield and with good regio- and stereoselectivity.

引用

页码：2211 / 2214

页数：4

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