Metal-free methods in the synthesis of macrocyclic Schiff bases

被引：418

作者：

Borisova, Nataliya E. ^{[1
]}

Reshetova, Marina D. ^{[1
]}

Ustynyuk, Yuri A. ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia

来源：

CHEMICAL REVIEWS | 2007年 / 107卷 / 01期

关键词：

D O I：

10.1021/cr0683616

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An overview is given of an approach toward the design and optimization of symmetrical and unsymmetrical macrocyclic Schiff bases. Focus is on data dealing with the synthesis of macrocyclic azomethines under metal-free conditions. Topics discussed include (1) the synthesis of macrocyclic Schiff bases of symmetric structure: [n+n]-condensation, n = 2-4, (2) the synthesis of macrocyclic Schiff bases of nonsymmetric structure: strategy for fragment-to-fragment assembling from enlarged building blocks and (3) anionic template effect in formation of macrocyclic ligand Schiff bases.

引用

页码：46 / 79

页数：34

共 196 条

[1] Synthesis of novel lariat azathia crown macrocycles containing two triazole rings and bis crown macrocycles containing four triazole rings [J].

Abbas, AA .

TETRAHEDRON, 2004, 60 (07) :1541-1548

[2] Liquid-liquid extraction of iron(III) and gallium(III) with macrocyclic Schiff bases containing bisphenol A subunits [J].

Abe, S ;

Mochizuki, J ;

Sone, T .

ANALYTICA CHIMICA ACTA, 1996, 319 (03) :387-392

[3] COPPER(II) COMPLEXES OF PYRROLE-CONTAINING SCHIFF-BASE MACROCYCLES - CRYSTAL AND MOLECULAR-STRUCTURES OF A MONONUCLEAR MACROCYCLIC COMPLEX, AND OF PYRROLE-2,5-DICARBALDEHYDE [J].

ADAMS, H ;

BAILEY, NA ;

FENTON, DE ;

MOSS, S ;

DEBARBARIN, COR ;

JONES, G .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (03) :693-699

[4] Unexpected ring contraction in the barium-assisted cyclocondensation of 2,6-diformylpyridine and N,N-bis(2-aminoethyl)-2-phenylethylamine [J].

Adams, H ;

Bailey, NA ;

Bertrand, P ;

Collinson, SR ;

Fenton, DE ;

Kitchen, SJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (06) :1181-1183

[5] Dinuclear copper(I) complexes of 24-membered bibracchial tetraimine Schiff base macrocycles derived from 2,5-diformylthiophene [J].

Adams, H ;

Bailey, NA ;

Collinson, SR ;

Fenton, DE ;

Hawley, JC ;

Kitchen, SJ .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 550 (1-2) :7-20

[6] Dinuclear silver(I) complexes of 24-membered bibracchial tetraimine Schiff base macrocycles derived from 2,5-diformylthiophene [J].

Adams, H ;

Bailey, NA ;

Bertrand, P ;

Collinson, SR ;

Fenton, DE ;

Kitchen, SJ .

INORGANICA CHIMICA ACTA, 1996, 250 (1-2) :139-148

[7] Lanthanide(III) macroacyclic and macrocyclic Schiff base complexes containing oxamidic groups [J].

Aguiari, A ;

Tamburini, S ;

Tomasin, P ;

Vigato, PA .

INORGANICA CHIMICA ACTA, 1997, 256 (02) :199-210

[8] MACROCYCLIC AND MACROACYCLIC COMPARTMENTAL SCHIFF-BASES - SYNTHESIS, CHARACTERIZATION, X-RAY STRUCTURE AND INTERACTION WITH METAL-IONS [J].

AGUIARI, A ;

BULLITA, E ;

CASELLATO, U ;

GUERRIERO, P ;

TAMBURINI, S ;

VIGATO, PA .

INORGANICA CHIMICA ACTA, 1992, 202 (02) :157-171

[9] MONONUCLEAR AND POLYNUCLEAR SCHIFF-BASE COMPLEXES DERIVED FROM POLYOXADIAMINES [J].

AGUIARI, A ;

BRIANESE, N ;

TAMBURINI, S ;

VIGATO, PA .

INORGANICA CHIMICA ACTA, 1995, 235 (1-2) :233-244

[10] NMR EVIDENCE FOR INTERCONVERSION BETWEEN 2 ENANTIOMERIC FORMS OF MACROCYCLIC SCHIFF-BASE LANTHANIDE(III) COMPLEXES THROUGH REVERSIBLE RING CONTRACTION AND EXPANSION [J].

AIME, S ;

BOTTA, M ;

CASELLATO, U ;

TAMBURINI, S ;

VIGATO, PA .

INORGANIC CHEMISTRY, 1995, 34 (23) :5825-5831

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