Exact analytical description of tracer exchange and particle conversion in single-file systems

被引:48
作者
Rodenbeck, C
Karger, J
Hahn, K
机构
[1] Universität Leipzig, Fakultät für Physik und Geowissenschaften, Leipzig, D-04103
来源
PHYSICAL REVIEW E | 1997年 / 55卷 / 05期
关键词
D O I
10.1103/PhysRevE.55.5697
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
The finite single-file system (diffusion in one dimension where the mutual passage of particles is inhibited) with particle exchange at the margins and an attractive nearest-neighbor particle-particle interaction is investigated. As the central quantity, the residence time distribution is introduced and related to experimentally observable quantities concerning tracer exchange and conversion. Exact equations determining these quantities are derived. The numerical solution yields the dependence of these quantities on the system parameters. In addition, the correlations in the single-file system are considered.
引用
收藏
页码:5697 / 5712
页数:16
相关论文
共 21 条
[1]  
[Anonymous], ANAL NUMERICAL METHO
[2]   POROUS CRYSTAL MEMBRANES [J].
BARRER, RM .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1990, 86 (07) :1123-1130
[3]   MEASUREMENT OF DIFFUSION COEFFICIENTS [J].
CARMAN, PC ;
HAUL, RAW .
PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1954, 222 (1148) :109-118
[4]   2-POINT CORRELATION-FUNCTIONS FOR A DISTINGUISHABLE PARTICLE HOPPING ON A UNIFORM ONE-DIMENSIONAL CHAIN [J].
FEDDERS, PA .
PHYSICAL REVIEW B, 1978, 17 (01) :40-46
[5]   Evidence for single file diffusion of ethane in the molecular sieve AlPO4-5 [J].
Gupta, V ;
Nivarthi, SS ;
McCormick, AV ;
Davis, HT .
CHEMICAL PHYSICS LETTERS, 1995, 247 (4-6) :596-600
[6]  
HAAG WO, 1982, FARADAY GENERAL DISC, V72, P317
[7]   Single-file diffusion observation [J].
Hahn, K ;
Karger, J ;
Kukla, V .
PHYSICAL REVIEW LETTERS, 1996, 76 (15) :2762-2765
[8]  
HODGKIN AL, 1955, J PHYS, V128, P91
[9]   SINGLE-FILE DIFFUSION AND REACTION IN ZEOLITES [J].
KARGER, J ;
PETZOLD, M ;
PFEIFER, H ;
ERNST, S ;
WEITKAMP, J .
JOURNAL OF CATALYSIS, 1992, 136 (02) :283-299
[10]   STRAIGHTFORWARD DERIVATION OF THE LONG-TIME LIMIT OF THE MEAN-SQUARE DISPLACEMENT IN ONE-DIMENSIONAL DIFFUSION [J].
KARGER, J .
PHYSICAL REVIEW A, 1992, 45 (06) :4173-4174