Photochemistry of imine-group VI carbene complexes:: Novel reactivity involving a cyclopentannulation reaction

被引：23

作者：

Campos, PJ ^{[1
]}

Sampedro, D ^{[1
]}

Rodríguez, MA ^{[1
]}

机构：

[1] Univ La Rioja, Dept Quim, Grp Sintesis Quim La Rioja, Unidad Asociada CSIC, E-26071 Logrono, Spain

来源：

ORGANOMETALLICS | 2000年 / 19卷 / 16期

关键词：

D O I：

10.1021/om000248x

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

3-Aza-1-chroma-1,3-butadiene undergoes photochemical [3 + 2] cyclopentannulation with alkenes and alkynes instead of the expected benzannulation or cyclobutannulation reactions, providing a good method for the synthesis of l-pyrroline and 2H-pyrrole derivatives. This photochemical reaction can be extended to molybdenum and tungsten carbene complexes.

引用

页码：3082 / 3084

页数：3