Synthesis of large-pore phenylene-bridged mesoporous organosilica using triblock copolymer surfactant

被引:207
作者
Goto, Y [1 ]
Inagaki, S [1 ]
机构
[1] Toyota Cent Res & Dev Labs Inc, Aichi 4801192, Japan
关键词
D O I
10.1039/b207825b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Periodic mesoporous benzene-silicas with large pores of 6.0 to 7.4 nm in diameter are synthesized using triblock copolymer as a template. These mesoporous materials have a well-defined hexagonal rod morphology and high thermal stability up to 823 K in air.
引用
收藏
页码:2410 / 2411
页数:2
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共 21 条
  • [1] Periodic mesoporous organosilicas with organic groups inside the channel walls
    Asefa, T
    MacLachlan, MJ
    Coombs, N
    Ozin, GA
    [J]. NATURE, 1999, 402 (6764) : 867 - 871
  • [2] ASEFA T, 2001, J AM CHEM SOC, V13, P2537
  • [3] Synthesis of periodic mesoporous organosilicas with block copolymer templates
    Burleigh, MC
    Markowitz, MA
    Wong, EM
    Lin, JS
    Gaber, BP
    [J]. CHEMISTRY OF MATERIALS, 2001, 13 (12) : 4411 - +
  • [4] Postsynthesis hydrothermal restructuring of M41S mesoporous molecular sieves in water
    Chen, LY
    Horiuchi, T
    Mori, T
    Maeda, K
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (08) : 1216 - 1222
  • [5] Mesoporous organosilicas prepared with PEO-containing triblock copolymers with different hydrophobic moieties
    Cho, EB
    Kwon, KW
    Char, K
    [J]. CHEMISTRY OF MATERIALS, 2001, 13 (11) : 3837 - +
  • [6] Novel templating synthesis of necklace-shaped mono- and bimetallic nanowires in hybrid organic-inorganic mesoporous material
    Fukuoka, A
    Sakamoto, Y
    Guan, S
    Inagaki, S
    Sugimoto, N
    Fukushima, Y
    Hirahara, K
    Iijima, S
    Ichikawa, M
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (14) : 3373 - 3374
  • [7] Cubic hybrid organic-inorganic mesoporous crystal with a decaoctahedral shape
    Guan, S
    Inagaki, S
    Ohsuna, T
    Terasaki, O
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (23) : 5660 - 5661
  • [8] An ordered mesoporous organosilica hybrid material with a crystal-like wall structure
    Inagaki, S
    Guan, S
    Ohsuna, T
    Terasaki, O
    [J]. NATURE, 2002, 416 (6878) : 304 - 307
  • [9] Novel mesoporous materials with a uniform distribution of organic groups and inorganic oxide in their frameworks
    Inagaki, S
    Guan, S
    Fukushima, Y
    Ohsuna, T
    Terasaki, O
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (41) : 9611 - 9614
  • [10] ISHII CY, 1999, CHEM COMMUN, P2539