Tris-β-diketones and related keto derivatives for use as building blocks in supramolecular chemistry

被引：23

作者：

Bray, David J.

Jolliffe, Katrina A. ^{[1
]}

Lindoy, Leonard F.

McMurtrie, John C.

机构：

[1] Univ Sydney, Sch Chem F11, Sydney, NSW 2006, Australia

[2] Univ Sydney, Sch Chem, Ctr Heavy Met Res, Sydney, NSW 2006, Australia

来源：

TETRAHEDRON | 2007年 / 63卷 / 09期

基金：

澳大利亚研究理事会;

关键词：

beta-diketone; tripodal scaffold; alkaline hydrolysis; tris-ketone;

D O I：

10.1016/j.tet.2006.12.071

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of three new tris-beta-diketones and some derivatives is reported. In two cases facile alkaline hydrolysis of the diketone moieties yielded the corresponding keto compounds. These are readily functionalised to provide tripodal ligands. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：1953 / 1958

页数：6

共 29 条

[1] SIR97:: a new tool for crystal structure determination and refinement
Altomare, A
Burla, MC
Camalli, M
Cascarano, GL
Giacovazzo, C
Guagliardi, A
Moliterni, AGG
Polidori, G
Spagna, R
[J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1999, 32 : 115 - 119
[2] What anions do inside a receptor's cavity: A trifurcate anion receptor providing both electrostatic and hydrogen-bonding interactions
Amendola, V
Boiocchi, M
Fabbrizzi, L
Palchetti, A
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (19) : 5648 - 5660
[3] [Anonymous], 1999, J. Appl. Crystallogr, DOI [DOI 10.1107/S0021889899006020, 10.1107/S0021889899006020]
[4] Assembly of a tri-silver metallo-capsule incorporating a tripodal tris-pyridyl ligand
Bray, DJ
Liao, LL
Antonioli, B
Gloe, K
Lindoy, LF
McMurtrie, JC
Wei, G
Zhang, XY
[J]. DALTON TRANSACTIONS, 2005, (12) : 2082 - 2083
[5] BRAY DJ, IN PRESS ADV INORGAN, V59, pCH1
[6] Bruker, 1995, SMART SAINT XREP AR
[7] Varying the frameworks of novel silver(I) coordination polymers with thioethers by altering the backbone or terminal groups of ligands
Bu, XH
Hou, WF
Du, M
Chen, W
Zhang, RH
[J]. CRYSTAL GROWTH & DESIGN, 2002, 2 (04) : 303 - 307
[8] Charles R. G., 1959, ORG SYNTH, V39, P61
[9] New discrete and polymeric supramolecular architectures derived from dinuclear (bis-β-diketonato) copper(II) metallocycles
Clegg, Jack K.
Gloe, Karsten
Hayter, Michael J.
Kataeva, Olga
Lindoy, Leonard F.
Moubaraki, Boujemaa
McMurtrie, John C.
Murray, Keith S.
Schilter, David
[J]. DALTON TRANSACTIONS, 2006, 33 (33) : 3977 - 3984
[10] Intra- and intermolecular second-sphere coordination chemistry: Formation of capsules, half-capsules, and extended structures with hexaaquo- and hexaamminemetal ions
Dalrymple, SA
Parvez, M
Shimizu, GKH
[J]. INORGANIC CHEMISTRY, 2002, 41 (26) : 6986 - 6996

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