New coupling reactions and phosphorylations using organozinc reagents

被引：21

作者：

Knochel, P

Langer, F

Longeau, A

Rottlander, M

Studemann, T

机构：

[1] Fachbereich Chemie der Philipps, Universität Marburg Hans, D-35032 Marburg, Meenvein-Strae

来源：

CHEMISCHE BERICHTE-RECUEIL | 1997年 / 130卷 / 08期

关键词：

zinc; chirality; cross-coupling; phosphorylations; catalysis;

D O I：

10.1002/cber.19971300802

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This Microreview on the chemistry of organozinc reagents starts by briefly showing the methods of preparation of organozinc compounds and then discusses the considerable synthetic utility of zinc organometallics for the formation of new carbon-carbon bonds in the presence of transition-metal catalysts. Finally, the use of organozinc chemistry for the preparation of polyfunctional and chiral phosphanes is described.

引用

页码：1021 / 1027

页数：7

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