Unexpected ligand displacement of Ru(cod)(cot) with trimethylphosphine to give fac-Ru(6-eta(1):1-3-eta(3)-C8H10)(PMe3)(3)

被引:19
作者
Hirano, M [1 ]
Marumo, T [1 ]
Miyasaka, T [1 ]
Fukuoka, A [1 ]
Komiya, S [1 ]
机构
[1] TOKYO UNIV AGR & TECHNOL, FAC TECHNOL, DEPT APPL CHEM, KOGANEI, TOKYO 184, JAPAN
关键词
D O I
10.1246/cl.1997.297
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Selective ligand displacement of the cod ligand in Ru(cod)(cot) (1) [cod: 1,5-cyclooctadiene, cot: 1,3,5-cyclooctatriene] with trimethylphosphine gives fac-Ru(6-eta(1):1-3-eta(3)-C8H10)(PMe3)(3)(3) in benzene at 50 degrees C.
引用
收藏
页码:297 / 298
页数:2
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