Co(II)-Co(II) paddlewheel complex with a redox-active ligand derived from TTF

被引：83

作者：

Benbellat, Noura

Gavrilenko, Konstantin S.

Le Gal, Yann

Cador, Olivier

Golhen, Stephane

Gouasmia, Abdelkrim

Fabre, Jean-Marc

Ouahab, Lahcene ^{[1
]}

机构：

[1] Univ Rennes 1, CNRS, UMR 6226, F-35042 Rennes, France

[2] Natl Acad Sci Ukraine, LV Pisarzhevskii Inst Phys Chem, UA-03039 Kiev, Ukraine

[3] Ctr Univ Tebessa, Lab Mat Organ & Heterochim, Tebessa 12000, Algeria

[4] ENSCM, Lab Chim Organ Heterochim & Mat Organ, UMR 5076, F-34296 Montpellier 5, France

来源：

INORGANIC CHEMISTRY | 2006年 / 45卷 / 26期

关键词：

D O I：

10.1021/ic061680v

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new trimethyltetrathiafulvalene (Me3TTF) derivative Me3TTF-CH=CH-py bearing a pyridyl was synthesized and coordinated to a cobalt(II) benzoate dimer, having paddlewheel core structure, leading to a complex formulated as Co-2(PhCOO)(4)(Me3TTF-CH=CH-py)(2). Single-crystal X-ray diffraction studies of the complex performed at 293 and 100 K evidenced the existence of a weak metal-metal interaction. Magnetic studies revealed an antiferromagnetic behavior, which is explained as the result of the direct exchange between metal centers.

引用

页码：10440 / 10442

页数：3

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