Synthesis, characterization and optical properties of a regioregular and soluble poly [3-(10-hydroxydecyl)-2,5-thienylene]

被引:21
作者
Lanzi, M [1 ]
Costa-Bizzarri, P [1 ]
Della-Casa, C [1 ]
Paganin, L [1 ]
Fraleoni, A [1 ]
机构
[1] Univ Bologna, Dipartimento Chim Ind & Mat, I-40136 Bologna, Italy
关键词
polyhydroxyalkylthiophene; regioregularity; post-functionalization;
D O I
10.1016/S0032-3861(02)00800-5
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The preparation of a regioregular trimethylsilanyloxydecyl 3-substituted polythiophene and its conversion to the corresponding hydroxydecyl polymer, which is soluble in common organic solvents, is described both in solution and in film. The chromic behaviour of the hydroxy functionalized polymer was investigated by UV-vis spectroscopy in different solvent/non-solvent mixtures and in the solid state by exposing the polymer adsorbed on hydroxylic matrices to methanol vapours. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:535 / 545
页数:11
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