A dinickel(II) complex of a [5,6]-unsymmetrical Schiff base compartmental ligand

被引:10
作者
Adams, H [1 ]
Clunas, S [1 ]
Fenton, DE [1 ]
机构
[1] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England
基金
英国工程与自然科学研究理事会;
关键词
crystal structure; dinuclear nickel(II) complex;
D O I
10.1016/S1387-7003(02)00639-1
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
In contrast to the reactions of [5,5]-unsymmetrical Schiff base compartmental ligands with Ni(ClO4)2 or Ni(BF4)21 which lead to cleavage of the iminic pendant arm of the ligand, the reaction of Ni(BF4)2 with the [5,5]-unsymmetrical Schiff base compartmental ligand2-{[(2-dimethylaminoethyl)ethylamino]-methyl}-4-methy1-6-[(2-pyridin-2-yl-ethylimino)methyl] phenol, HL7, gave a dinuclear nickel(II) complex in which the integrity of the ligand was retained. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:1063 / 1065
页数:3
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