Environmentally benign batteries based on organic radical polymers

被引：75

作者：

Nishide, Hiroyuki ^{[1
]}

Koshika, Kenichiroh ^{[1
]}

Oyaizu, Kenichi ^{[1
]}

机构：

[1] Waseda Univ, Dept Appl Chem, Tokyo 1698555, Japan

来源：

PURE AND APPLIED CHEMISTRY | 2009年 / 81卷 / 11期

关键词：

electrode-active materials; functional polymers; green chemistry; radical molecules; secondary batteries; N-TYPE; RECHARGEABLE BATTERIES; P-TYPE;

D O I：

10.1351/PAC-CON-08-12-03

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A radical polymer is an aliphatic organic polymer bearing densely populated unpaired electrons in the pendant robust radical groups per repeating unit. These radicals' unpaired electrons are characterized by very fast electron-transfer reactivity, allowing reversible charging as the electrode-active materials for secondary batteries. Organic-based radical batteries have several advantages over conventional batteries, such as increased safety, adaptability to wet fabrication processes, easy disposability, and capability of fabrication from less-limited resources, which are described along the fashion of green chemistry.

引用

页码：1961 / 1970

页数：10

共 23 条

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