Fluorous glycol derivatives: novel carbonyl protective groups

被引：7

作者：

Huang, YG

Qing, FL

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, Shanghai 200032, Peoples R China

[2] Donghua Univ, Coll Chem & Chem Engn, Shanghai 200051, Peoples R China

来源：

TETRAHEDRON | 2004年 / 60卷 / 38期

基金：

中国国家自然科学基金;

关键词：

fluorous synthesis; carbonyl protective groups;

D O I：

10.1016/j.tet.2004.07.031

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Fluorous glycol derivatives 5 were prepared and evaluated as reagents for the protection of carbonyl groups for use in fluorous synthesis. The acetals formed from fluorous diol 5b (Rf = n-C8F17) with carbonyl compounds can be separated and purified by simple fluorous-organic extraction. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：8341 / 8346

页数：6

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