From Vinylidene Fluoride (VDF) to the Applications of VDF-Containing Polymers and Copolymers: Recent Developments and Future Trends

被引:634
作者
Ameduri, Bruno [1 ]
机构
[1] Ecole Natl Super Chim Montpellier, CNRS, UMR 5253, Inst Charles Gerhardt, F-34296 Montpellier 5, France
关键词
FLUORINATED MONOMERS BEARING; REACTIVE LATERAL GROUP; TRANSFER RADICAL POLYMERIZATION; PROTON-EXCHANGE MEMBRANES; IODINE TRANSFER POLYMERIZATION; SUPERCRITICAL CARBON-DIOXIDE; HOMOGENEOUS PHASE POLYMERIZATION; NUCLEAR MAGNETIC-RESONANCE; SWIFT HEAVY-ION; PVDF-G-PSSA;
D O I
10.1021/cr800187m
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Some of the latest developments and potential trends in the field of vinylidene fluoride (VDF) and applications of VDF-containing polymers and copolymers are discussed. A number of syntheses have been found suitable to prepare VDF for different applications. It is expected that new fluropolymeric materials and new curing chemistry will be developed in the future due to continued focus on severe service conditions and improvements in wide range of temperature damping characteristics and low-temperature resilience. Blends of fluoropolymers with other polymers and recyclability features are also expected to contribute to their successful application in many engineering and aggressive service environments. VDF has gained significance as one of the most suitable fluoropolymers, as it is a versatile, nontoxic, and environmentally friendly gaseous monomer that can be easily homopolymerized and copolymerized in the presence of radicals.
引用
收藏
页码:6632 / 6686
页数:55
相关论文
共 612 条
[1]   Crystallinity and morphology of PVdF-HFP-based gel electrolytes [J].
Abbrent, S ;
Plestil, J ;
Hlavata, D ;
Lindgren, J ;
Tegenfeldt, J ;
Wendsjö, Å .
POLYMER, 2001, 42 (04) :1407-1416
[2]  
ABUSLEME JA, 1995, Patent No. 5569728
[3]   Continuous copolymerization of vinylidene fluoride with hexafluoropropylene in Supercritical carbon dioxide: Low hexafluoropropylene content semicrystalline copolymers [J].
Ahmed, Tamer S. ;
DeSimone, Joseph M. ;
Roberts, George W. .
MACROMOLECULES, 2007, 40 (26) :9322-9331
[4]   Copolymerization of vinylidene fluoride with hexafluoropropylene in supercritical carbon dioxide [J].
Ahmed, TS ;
DeSimone, JM ;
Roberts, GW .
MACROMOLECULES, 2006, 39 (01) :15-18
[5]  
AHMED TS, 2007, POLYM PREPR, V48, P194
[6]   Solid-state 19F MAS and 1H → 19F CP/MAS NMR study of the phase transition behavior of vinylidene fluoride-trifluoroethylene copolymers:: 1.: Uniaxially drawn films of VDF 75% copolymer [J].
Aimi, K ;
Ando, S ;
Avalle, P ;
Harris, RK .
POLYMER, 2004, 45 (07) :2281-2290
[7]   FLUOROELASTOMERS DEPENDENCE OF RELAXATION PHENOMENA ON COMPOSITION [J].
AJROLDI, G ;
PIANCA, M ;
FUMAGALLI, M ;
MOGGI, G .
POLYMER, 1989, 30 (12) :2180-2187
[8]  
AKIMOTO H, 2000, Patent No. 07732
[9]   Size fractionation of metal nanoparticles by membrane filtration [J].
Akthakul, A ;
Hochbaum, AI ;
Stellacci, F ;
Mayes, AM .
ADVANCED MATERIALS, 2005, 17 (05) :532-+
[10]  
ALBIN JR, 1964, Patent No. 3136745