Large H2 storage capacity of a new polyhedron-based metal-organic framework with high thermal and hygroscopic stability

被引：81

作者：

Hong, Seunghee ^{[1
]}

Oh, Minhak ^{[1
]}

Park, Mira ^{[1
]}

Yoon, Ji Woong ^{[2
]}

Chang, Jong-San ^{[2
]}

Lah, Myoung Soo ^{[1
]}

机构：

[1] Hanyang Univ, Dept Chem & Appl Chem, Ansan 426791, Kyunggi Do, South Korea

[2] Korea Res Inst Chem Technol, Taejon 305600, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 36期

关键词：

BUILDING-BLOCKS SBBS; HYDROGEN STORAGE; SURFACE-AREA; SITES; ADSORPTION; DESIGN; UNITS; CATENATION; NETWORKS; CRYSTALS;

D O I：

10.1039/b909250a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two metal-organic frameworks (MOFs) based on metal-organic cuboctahedra were prepared using a rigid C-3 symmetric ligand, where Zn polyhedron-based MOF (PMOF-2(Zn)) did not show any significant gas sorption behavior, whereas the isostructural Cu polyhedron-based MOF (PMOF-2(Cu)) showed a large surface area of similar to 4180 m(2) g(-1), high hydrothermal stability, and very promising H-2 sorption properties.

引用

页码：5397 / 5399

页数：3

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